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第 16 章

酸塩基と溶解度平衡

共通イオン効果
共通イオン効果
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of ...
緩衝液
緩衝液
A solution containing appreciable amounts of a weak conjugate acid-base pair is called a buffer solution, or a buffer. Buffer solutions resist a change in ...
ヘンダーソン-ハッセルバルヒ式
ヘンダーソン-ハッセルバルヒ式
The ionization-constant expression for a solution of a weak acid can be written as: Rearranging to solve for [H3O+] yields: Taking the negative ...
緩衝液中のpHの変化の計算
緩衝液中のpHの変化の計算
A buffer can prevent a sudden drop or increase in the pH of a solution after the addition of a strong acid or base up to its buffering capacity; however, ...
緩衝液の有効性
緩衝液の有効性
Buffer solutions do not have an unlimited capacity to keep the pH relatively constant . Instead, the ability of a buffer solution to resist changes in pH ...
滴定計算:強酸-強塩基
滴定計算:強酸-強塩基
Calculating pH for Titration Solutions: Strong Acid/Strong Base A titration is carried out for 25.00 mL of 0.100 M HCl (strong acid) with 0.100 M of a ...
滴定計算:弱酸-弱塩基
滴定計算:弱酸-弱塩基
Calculating pH for Titration Solutions: Weak Acid/Strong Base For the titration of 25.00 mL of 0.100 M CH3CO2H with 0.100 M NaOH, the reaction can be ...
指示薬
指示薬
Certain organic substances change color in dilute solution when the hydronium ion concentration reaches a particular value. For example, phenolphthalein ...
多価酸の滴定
多価酸の滴定
A polyprotic acid contains more than one ionizable hydrogen and undergoes a stepwise ionization process.  If the acid dissociation constants of the ...
溶解平衡
溶解平衡
Solubility equilibria are established when the dissolution and precipitation of a solute species occur at equal rates. These equilibria underlie many ...
溶解性に影響する因子
溶解性に影響する因子
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of ...
錯体イオンの形成
錯体イオンの形成
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition ...
イオンの沈殿
イオンの沈殿
Predicting Precipitation The equation that describes the equilibrium between solid calcium carbonate and its solvated ions is: It is important to realize ...
定性分析
定性分析
For solutions containing mixtures of different cations, the identity of each cation can be determined by qualitative analysis. This technique involves a ...
酸塩基滴定曲線
酸塩基滴定曲線
A titration curve is a plot of some solution property versus the amount of added titrant. For acid-base titrations, solution pH is a useful property to ...
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