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第 13 章

化学動力学

反応速度
反応速度
The rate of reaction is the change in the amount of a reactant or product per unit time. Reaction rates are therefore determined by measuring the time ...
反応速度の測定
反応速度の測定
Polarimetry finds application in chemical kinetics to measure the concentration and reaction kinetics of optically active substances during a chemical ...
濃度と反応速度の関係性
濃度と反応速度の関係性
The rate of a reaction is affected by the concentrations of reactants. Rate laws (differential rate laws) or rate equations are mathematical expressions ...
反応順序の決定
反応順序の決定
Rate laws describe the relationship between the rate of a chemical reaction and the concentration of its reactants. In a rate law, the rate constant k and ...
積分速度則:反応濃度と時間
積分速度則:反応濃度と時間
While the differential rate law relates the rate and concentrations of reactants, a second form of rate law called the integrated rate law relates ...
反応の半減期
反応の半減期
The half-life of a reaction (t1/2) is the time required for one-half of a given amount of reactant to be consumed. In each succeeding half-life, half of ...
温度依存の反応速度
温度依存の反応速度
The Collision Theory Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. ...
アレニウスプロット
アレニウスプロット
The Arrhenius equation relates the activation energy and the rate constant, k, for chemical reactions. In the Arrhenius equation, k = Ae−Ea/RT, R is ...
反応メカニズム
反応メカニズム
Chemical reactions often occur in a stepwise fashion, involving two or more distinct reactions taking place in a sequence. A balanced equation indicates ...
反応速度の決定ステップ
反応速度の決定ステップ
Relating Reaction Mechanisms In a multistep reaction mechanism, one of the elementary steps progresses significantly slower than the others. This slowest ...
触媒作用
触媒作用
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed ...
酵素
酵素
Inside living organisms, enzymes act as catalysts for many biochemical reactions involved in cellular metabolism. The role of enzymes is to reduce the ...
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