JoVE Logo

サインイン

Chapter 13

Molecular Vibrational Spectroscopy

赤外線 (IR) 分光法: 概要
赤外線 (IR) 分光法: 概要
When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation ...
IR 分光法: 分子振動 - 概要
IR 分光法: 分子振動 - 概要
When Infrared (IR) radiation passes through a covalently bonded molecule, the bonds transition from lower to higher vibrational levels. The fundamental ...
IR 分光法: 分子振動のフックの法則近似
IR 分光法: 分子振動のフックの法則近似
A covalently bonded heteronuclear diatomic molecule can be modeled as two vibrating masses connected by a spring. The vibrational frequency of the bond ...
IR 分光計
IR 分光計
There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR ...
赤外線スペクトル
赤外線スペクトル
When infrared (IR) radiation passes through a molecule, the bonds stretch or bend by absorbing the radiation. This absorption creates the molecule's ...
IR吸収周波数:ハイブリダイゼーション
IR吸収周波数:ハイブリダイゼーション
Hydrocarbons such as alkanes, alkenes, and alkynes show characteristic C–H stretching absorption bands. These IR stretching frequencies depend on ...
IR吸収周波数:非局在化
IR吸収周波数:非局在化
Electron delocalization refers to the distribution of electrons across multiple atoms within a molecule rather than being confined to a single atom or ...
IR 周波数領域: X-H 伸縮
IR 周波数領域: X-H 伸縮
In IR spectroscopy, signals produced by the X−H bonds (such as C−H, O−H, or N−H) can be observed in the frequency range of  ...
IR 周波数領域: アルキンとニトリルの伸縮
IR 周波数領域: アルキンとニトリルの伸縮
Both alkyne (C≡C) and nitrile (C≡N) functional groups contain triple bonds and show stretching absorptions around the wavenumber range of 2100 ...
IR周波数領域:アルケンおよびカルボニルストレッチ
IR周波数領域:アルケンおよびカルボニルストレッチ
Double bonds in alkenes and carbonyl compounds exhibit stretching frequencies in the diagnostic region of the IR spectrum. In addition, alkenes exhibit ...
IR 周波数領域: 指紋領域
IR 周波数領域: 指紋領域
IR spectra are divided into two main regions: the diagnostic region and the fingerprint region. The diagnostic region of the spectrum lies above 1500 ...
IR スペクトルのピーク強度: IR 活性結合の量
IR スペクトルのピーク強度: IR 活性結合の量
When infrared radiation is passed through a molecule, absorption occurs if the molecule's vibration leads to a substantial change in its bond dipole ...
IR スペクトルのピーク強度: 双極子モーメント
IR スペクトルのピーク強度: 双極子モーメント
The dipole moment of a bond is the product of the partial charge on either atom and the distance between them. Dipole moments influence the efficiency of ...
IR スペクトルのピークの広がり: 水素結合
IR スペクトルのピークの広がり: 水素結合
The vibrational frequency of a bond is directly proportional to its bond strength. As a result, stronger bonds vibrate at higher frequencies, while weaker ...
IR スペクトルのピーク分割: 対称振動と非対称振動
IR スペクトルのピーク分割: 対称振動と非対称振動
Identical bonds within a polyatomic group can stretch symmetrically (in-phase) or asymmetrically (out-of-phase). Similar to hydrogen bonding, these ...
IR 分光法の用途: 概要
IR 分光法の用途: 概要
The non-destructive nature and ability to provide valuable chemical information make IR spectroscopy a versatile technique with broad applications in ...
減衰全反射率(ATR)赤外分光法:概要
減衰全反射率(ATR)赤外分光法:概要
Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely ...
ラマン分光法:概要
ラマン分光法:概要
The underlying principle of Raman spectroscopy is based on the interaction between light and matter, specifically molecules' inelastic scattering of ...
ラマン分光法: 計測機器
ラマン分光法: 計測機器
A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector. The monochromatic laser ...
JoVE Logo

個人情報保護方針

利用規約

一般データ保護規則

研究

教育

JoVEについて

Copyright © 2023 MyJoVE Corporation. All rights reserved